Conduction occurs primarily in solids where vibrating particles transfer kinetic energy to their neighbors through collisions. Metals are superior conductors because their delocalised electrons can move freely through the lattice, rapidly spreading thermal vibrations throughout the material.
Convection is the transfer of heat through fluids (liquids and gases) via the movement of the fluid itself. When a fluid is heated, it expands and becomes less dense, causing it to rise while cooler, denser fluid sinks to take its place, creating a continuous convection current.
Radiation is the only method of heat transfer that does not require particles, as it travels through a vacuum via infrared electromagnetic waves. Surfaces that are dark and matte are excellent absorbers and emitters of infrared, whereas light, shiny surfaces reflect radiation and are poor emitters.
Efficiency is a numerical measure of how much input energy is converted into useful output, expressed as a ratio or a percentage. It is calculated by dividing the useful energy output by the total energy input, ensuring that the result is never greater than 100% due to unavoidable dissipation.
Formula:
To improve efficiency, engineers focus on reducing wasted transfers, such as using lubrication to reduce friction (mechanical waste) or insulation to reduce thermal dissipation.
Understanding the difference between temperature and thermal energy is vital: temperature is the average kinetic energy of particles, while thermal energy is the total energy of all particles in a substance. A large iceberg has more thermal energy than a cup of boiling water because it contains vastly more molecules, even though its temperature is lower.
| Feature | Conduction | Convection | Radiation |
|---|---|---|---|
| Medium | Solids (mostly) | Fluids (Liquids/Gases) | Vacuum/Transparent media |
| Mechanism | Particle collisions | Bulk fluid movement | Electromagnetic waves |
| Speed | Slow to Moderate | Moderate | Speed of Light |
When describing energy transfers, always use the format: 'Energy is transferred from the [Store A] to the [Store B] via the [Pathway]'. This structure ensures you identify all three components required by examiners to earn full marks.